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Top facts about Kiev (Kyiv) Being the largest city of Ukraine, Kiev (Kyiv) is a leading industrial and commercial center of the country. Kiev's major industries include: food processing (especially processing of beet sugar), metallurgy, manufacture of machinery, machine tools, rolling stock, chemicals, building materials, and textiles. The development of Ukrainian economy gave impulse to business activity of the city. There are a lot of new office centers, banks, trade exhibition centers and other commercial enterprises appearing in the city nowadays. Kiev (Kyiv) is served by a good transportation network. Trunk railways and all-weather roads link Kiev to Moscow, Kharkiv and the Donets Basin, southern and western Ukraine, and Poland. Within Kiev city itself there is efficient subway, rail, and bus service. The Dnieper River is navigable about nine months of the year, and Kiev’s Boryspil airport operates flights to other Ukrainian cities and to cities in Europe, Asia, and North America.